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Production of cold ions
Tran, Thuy Dung ; Plašil, Radek (advisor) ; Roučka, Štěpán (referee)
1 Abstract: For understanding of the evolution of chemical composition in cold interstellar gas clouds, it is necessary to study the ion-molecule reactions at temperatures from 10 K to 300 K at low pressures. The Ion Trap equipment, which is available in the laboratory of the Department of Surface and Plasma Science, allows this type of experiment. The main element of the Ion Trap is a 22-pole radiofrequency trap that examined reactions take place. For capturing ions in the trap, they need to be well focused in space, time and energy. To meet these conditions, it is necessary to find a suitable parameters of the source, which is used in the laboratory. The aim of this bachelor thesis is the design of optimized ion source and then using the program in LabVIEW to optimize the ion source N+ .
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Water formation in reactions of anions and/or cations with molecular hydrogen at low temperature
Tran, Thuy Dung ; Plašil, Radek (advisor)
In the present work, the results of the experimental study of reactions of ions with molecular hydrogen in the temperature range 15 - 300 K using a 22-pole ion trap apparatus are presented. The reaction of OD- with para-enriched hydrogen was studied using a combination of the 22-pole ion trap apparatus with a para-hydrogen generator. Also reactions of O- with H2, D2, and HD were studied. These reactions have a channel of water production and a channel of hydrogen or deuterium transfer. Another field of study was a sequence of reactions of oxygen hydride cations with H2 and D2 which leads to the production of H3O+ or its isotopic variant, specifically reactions OH+ with H2, H2O+ with H2, D2O+ with H2, and D2O+ with D2. This reaction chain can be followed by the electron recombination of H3O+ or its isotopologue, which has a channel of water production.
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Water formation in reactions of anions and/or cations with molecular hydrogen at low temperature
Tran, Thuy Dung ; Plašil, Radek (advisor)
In the present work, the results of the experimental study of reactions of ions with molecular hydrogen in the temperature range 15 - 300 K using a 22-pole ion trap apparatus are presented. The reaction of OD- with para-enriched hydrogen was studied using a combination of the 22-pole ion trap apparatus with a para-hydrogen generator. Also reactions of O- with H2, D2, and HD were studied. These reactions have a channel of water production and a channel of hydrogen or deuterium transfer. Another field of study was a sequence of reactions of oxygen hydride cations with H2 and D2 which leads to the production of H3O+ or its isotopic variant, specifically reactions OH+ with H2, H2O+ with H2, D2O+ with H2, and D2O+ with D2. This reaction chain can be followed by the electron recombination of H3O+ or its isotopologue, which has a channel of water production.
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Water formation in reactions of anions and/or cations with molecular hydrogen at low temperature
Tran, Thuy Dung ; Plašil, Radek (advisor) ; Španěl, Patrik (referee) ; Rubovič, Peter (referee)
In the present work, the results of the experimental study of reactions of ions with molecular hydrogen in the temperature range 15 - 300 K using a 22-pole ion trap apparatus are presented. The reaction of OD- with para-enriched hydrogen was studied using a combination of the 22-pole ion trap apparatus with a para-hydrogen generator. Also reactions of O- with H2, D2, and HD were studied. These reactions have a channel of water production and a channel of hydrogen or deuterium transfer. Another field of study was a sequence of reactions of oxygen hydride cations with H2 and D2 which leads to the production of H3O+ or its isotopic variant, specifically reactions OH+ with H2, H2O+ with H2, D2O+ with H2, and D2O+ with D2. This reaction chain can be followed by the electron recombination of H3O+ or its isotopologue, which has a channel of water production.
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Reactions of cations with hydrogen atoms and molecules at low temperatures
Tran, Thuy Dung ; Plašil, Radek (advisor) ; Kaňka, Adolf (referee)
This thesis is concerned about ion-molecular reactions at low temperatures, which are important the fully understand the chemical evolution in interstellar medium. For realization of experimental part of thesis has been used the apparatus of 22-pole radiofrequency ion trap, which allows study the rate constant of reactions at temperatures 10 - 100 K. Thesis contains measuring results of reaction NH+ + H → N+ + H2, which follows the previous study of reaction N+ + H2 → NH+ + H on the same apparatus, description of the apparatus and the general introduction.
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Production of cold ions
Tran, Thuy Dung ; Plašil, Radek (advisor) ; Roučka, Štěpán (referee)
1 Abstract: For understanding of the evolution of chemical composition in cold interstellar gas clouds, it is necessary to study the ion-molecule reactions at temperatures from 10 K to 300 K at low pressures. The Ion Trap equipment, which is available in the laboratory of the Department of Surface and Plasma Science, allows this type of experiment. The main element of the Ion Trap is a 22-pole radiofrequency trap that examined reactions take place. For capturing ions in the trap, they need to be well focused in space, time and energy. To meet these conditions, it is necessary to find a suitable parameters of the source, which is used in the laboratory. The aim of this bachelor thesis is the design of optimized ion source and then using the program in LabVIEW to optimize the ion source N+ .
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